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Oxygen Permeability of Nanocomposite‐Based Polyolefin Films
Author(s) -
FujiyamaNovak Jane H.,
Rufino Vivianne,
Amaral Rafael A.,
Habert A. Claudio,
Borges Cristiano P.,
Mano Bárbara
Publication year - 2016
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201600001
Subject(s) - polyolefin , oxygen permeability , materials science , nanocomposite , montmorillonite , polypropylene , polyethylene , dissolution , scanning electron microscope , polymer , oxygen , composite material , chemical engineering , solvent , polymer chemistry , chemistry , organic chemistry , layer (electronics) , engineering
Summary Polyethylene and polypropylene are vastly employed for packaging due to their high versatility and low cost. However, their films are permeable at different degree to small molecules like gases and the use of additives improves the barrier properties. Therefore, the aim of this work is to investigate the effect of organically modified montmorillonite on oxygen transport properties of PE and PP films. Nanocomposites were prepared by means of polymer dissolution in organic solvent and subsequent nanoparticle addition at 3, 5 and 10% (w/w). Scanning electron microscopy images of the films indicate the presence of microcavities and some agglomerated nanoclay. On the other hand, X‐rays diffraction analysis shows clay in well‐dispersed state independent of polyolefin type. Enhancement of oxygen barrier is achieved, but this property is dependent on the nanoclay content, polyolefin type and film morphology.