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Crosslinking Copolymerization of Vinyl Monomers Using Non‐Vinyl Crosslinker: Morpholine Substituted Poly (vinyl methyl ketone)
Author(s) -
Ince Ahmet,
Bicak Niyazi
Publication year - 2015
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201400149
Subject(s) - methyl vinyl ketone , vinyl polymer , copolymer , monomer , polymer chemistry , morpholine , styrene , polymerization , vinyl ester , polymer , materials science , chemistry , organic chemistry , catalysis
Summary Morpholine substituted poly(vinyl methyl ketone) (MSP) is presented as non‐vinyl crosslinker forming insoluble polymers in polymerization of vinyl monomers. In this process, crosslinking occurs via double bonds in situ formed by thermal de‐amination of MSP above 70 °C as demonstrated in polymerization of methylmethacrylate (MMA), styrene and 4‐vinyl pyridine (4‐VP) monomers.