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Metallic Nanocatalysts Embedded within p H ‐Responsive Polymeric Microgels and Deposition onto Solid Substrates
Author(s) -
Kaliva Maria,
Frysali Melani A.,
Flouraki Chara,
Papoutsakis Lampros,
Vamvakaki Maria,
Anastasiadis Spiros H.
Publication year - 2013
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201300078
Subject(s) - nanomaterial based catalyst , copolymer , polymer chemistry , nanoparticle , acrylic acid , chemical engineering , materials science , monomer , aqueous solution , methacrylate , polyelectrolyte , substrate (aquarium) , metal , emulsion , chemistry , polymer , nanotechnology , organic chemistry , composite material , geology , engineering , oceanography , metallurgy
Summary Palladium (Pd) and ruthenium (Ru) catalytically active nanoparticles are synthesized using as templates pH‐sensitive microgels based on poly(2‐(diethylamino)ethyl methacrylate), PDEAEMA, and poly(acrylic acid), PAA, respectively. The PDEAEMA and PAA microgel particles are prepared by emulsion copolymerization of a functional monomer with a cross‐linker in the presence of a stabilizer in aqueous media. The incorporation of Pd and Ru nanoparticles within PDEAEMA and PAA is achieved using metal precursors that interact with the amino‐ or carboxyl‐groups of PDEAEMA and PAA, respectively; the metal precursors are subsequently reduced within the microgel to produce the metal nanocatalysts. The attachment of the microgel particles onto glass substrate surfaces, which can potentially be used as the walls of microfluidic reactors, is studied by exploring the Pickering emulsion process. The attached particles are tested for stability and endurance when immersed in pure water for extended periods of time and when rinsed extensively with pure water.