Synthesis of Model Network Hydrogels via Tetrazine‐ O lefin Inverse Electron Demand Diels‐ A lder Cycloaddition | Zendy

Cok Alexandra M. | Zendy; Zhou Huaxing | Zendy; Johnson Jeremiah A. | Zendy

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Synthesis of Model Network Hydrogels via Tetrazine‐ O lefin Inverse Electron Demand Diels‐ A lder Cycloaddition

Author(s) -

Cok Alexandra M.,

Zhou Huaxing,

Johnson Jeremiah A.

Publication year - 2013

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.201300008

Subject(s) - self healing hydrogels , tetrazine , cycloaddition , inverse , olefin fiber , click chemistry , chemistry , peg ratio , ethylene glycol , polymer chemistry , organic chemistry , polymer , mathematics , geometry , catalysis , finance , economics

Summary The formation of poly(etheylene glycol) (PEG) model network hydrogels via an A 2 + B 3 inverse‐electron‐demand tetrazine‐olefin Diels‐Alder cycloaddition is reported. This method provides an efficient, additive‐free, colorimetric gelation reaction that will complement other “click chemistry” approaches to model network synthesis.

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