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Novel Peroxide Containing Maleinate Surface‐Active Monomers for Obtaining Reactive Polymers
Author(s) -
Borzenkov Mykola,
Hevus Orest
Publication year - 2012
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201250508
Subject(s) - maleic anhydride , monomer , polymer chemistry , micelle , peroxide , styrene , benzoyl peroxide , critical micelle concentration , ethylene glycol , copolymer , propane , polymer , ether , materials science , chemistry , organic chemistry , aqueous solution
Novel surface‐active monomers were synthesized by successive treatment of tert‐butylperoxy‐6‐hydroxyhexanoate with maleic anhydride, 1,3‐propane sultone and triethylamine or with maleic anhydride and poly(ethylene glycol) methyl ether. The surface‐active properties of monomers were studied. The critical micelle concentrations (cmc) as well as the surface tension at the cmc were determined for obtained monomers. The synthesized compounds were shown to be suitable reactive surfactants for obtaining styrene latexes.