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Refractory Metal‐Containing Polymers and Nanocomposites: Preparation and Properties
Author(s) -
Dzhardimalieva Gulzhian I.,
Pomogailo Svetlana I.,
Golubeva Nina D.,
Pomogailo Anatolii D.
Publication year - 2011
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201150614
Subject(s) - tantalum , polymer , monomer , thermal decomposition , materials science , nanocomposite , acrylate , polymerization , niobium , polymer chemistry , metal , elemental analysis , thermal analysis , refractory metals , chemical engineering , inorganic chemistry , organic chemistry , chemistry , nanotechnology , thermal , metallurgy , physics , meteorology , engineering , composite material
Abstract Summary: Novel polymers containing refractory metal in the main chain or side chains can be prepared. An attractive approach is polymerization of the Hf (Ta, Nb)‐monomers with (meth)acrylate, fumarate or monomethylmethacrylate ethyleneglycol groups, synthesized for the first time in this study. New types of hafnium (tantalum, niobium)‐containing nanocomposites are prepared by combining polymer synthesis and controlled thermolysis. The composition and structure of the synthesized metal‐containing precursors and thermolysis products are determined by elemental analysis, IR and 1 H‐NMR spectroscopies, X‐ray diffraction and TEM analysis.