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Characterization of PVC‐Tetraruthenated Metalloporphyrins Modified Electrodes: Application as Electrocatalyst in the Nitrite Reduction
Author(s) -
Calfumán Karla,
Dreyse Paulina,
García Camilo,
Aguirre Maria J.,
Beltrán Tomás,
Guillamón Eva,
Sorribes Iván,
Vicent Cristian,
Llusar Rosa,
Isaacs Mauricio
Publication year - 2011
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201150613
Subject(s) - electrocatalyst , overpotential , hydroxylamine , electrolysis , nitrite , cyclic voltammetry , electrochemistry , electrode , inorganic chemistry , bulk electrolysis , glassy carbon , materials science , hydrazine (antidepressant) , chemically modified electrode , chemistry , reference electrode , organic chemistry , nitrate , chromatography , electrolyte
Summary: This paper describes the electrochemical reduction of nitrite ion in 0.1 M NaClO 4 , on glassy carbon or ITO electrodes modified with mixtures PVC‐ tetraruthenated metalloporphyrins. This electrode is able to keep the extraordinary electrocatalytic properties of the macrocycle allowing multielectronic transfers and a great stability as a consequence of the inclusion of the macrocycles into a polymeric support such as PVC. On the other hand, the electrochemical reduction of nitrite ion on these modified electrodes studied by cyclic voltammetry shows an enhancement in the current values and lower overpotential compared with the activity of the bare glassy carbon electrode. Controlled potential electrolysis experiments verify the production of ammonia, hydrazine and hydroxylamine, showing the electrocatalytic character and the stability of this modified electrode.