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Synthesis of New Anionic and Cationic Polymerizable Surfactants for Emulsion Polymerization of Styrene
Author(s) -
Mekki Sofiane,
SaïdiBesbes Salima,
Elaïssari Abdelhamid,
Valour JeanPierre,
Derdour Aïcha
Publication year - 2010
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.201051015
Subject(s) - cationic polymerization , potassium persulfate , emulsion polymerization , styrene , polymer chemistry , polymerization , emulsion , persulfate , chemistry , copolymer , materials science , organic chemistry , polymer , catalysis
New anionic and cationic maleic surfmers containing a benzyl or p‐vinylbenzyl hydrophobic tail were prepared and characterized. The behaviour of benzyl maleate hemiester in the emulsion polymerization process of styrene has been studied in the presence of potassium persulfate as initiator. The effect of surfmer concentration on particle diameter was particularly investigated.