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Application of Input Trajectory Optimisation of Ziegler‐Natta Catalysed Gas‐Phase Olefin Polymerisation Reactor Systems
Author(s) -
Rawatlal Randhir
Publication year - 2009
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200951101
Subject(s) - residence time distribution , residence time (fluid dynamics) , continuous stirred tank reactor , work (physics) , natta , mechanics , flow (mathematics) , olefin fiber , trajectory , population , materials science , plug flow reactor model , nuclear engineering , catalysis , polymerization , thermodynamics , chemistry , engineering , chemical engineering , physics , polymer , organic chemistry , composite material , demography , astronomy , sociology , geotechnical engineering
Summary : In this work, an alternative formulation of the Population Balance Model (PBM) is proposed to simplify the mathematical structure of the reactor model. The method is based on the segregation approach applied to the recently developed unsteady state Residence Time Distribution (RTD). It is shown that the model can predict the performance of a reactor system under unsteady flow and composition conditions. Case studies involving time‐varying catalyst flowrates, reactor temperature and reactor pressure were simulated and found to predict reactor performance with reasonable accuracy. The model was used to propose a grade transition strategy that could reduce transition time by as much as two hours.