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Electrostatically‐driven Ordering in Model Dendrimer Polyelectrolytes: Effects of Concentration
Author(s) -
Karatasos K.,
Krystallis M.
Publication year - 2009
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200950405
Subject(s) - dendrimer , counterion , polyelectrolyte , chemical physics , volume fraction , colloid , chemistry , macromolecule , chemical engineering , materials science , polymer chemistry , ion , organic chemistry , polymer , biochemistry , engineering
Abstract In this study we extend our previous work in the self‐organization of dendrimer polyelectrolytes (Macromolecules, 2008 , 41 , 225) by examining the effects of dendrimer concentration and/or total volume fraction in the ordering process and the resulting structure, in the arrangement of counterions and dendrimer beads and in the diffusive motion of dendrimers at different strengths of Coulombic interactions. It is found that as long as the total volume fraction remains low (i.e. no jamming phenomena intervene) the symmetry of the resulted cubic phases is unaltered. At a higher volume fraction and at the strong electrostatic regime a kinetic arrest of the dendrimer molecules much in analogy to a colloidal glass‐like transition is observed, inhibiting thus the ordering process. Changes in the strength of electrostatic interactions and dendrimer concentration induces a systematic variation of the counterion ‐ counterion and the counterion ‐ charged‐dendrimer‐bead spatial arrangement. These findings are in qualitative agreement with previous studies in systems with very different structural details of the considered solutes, indicating a more general behaviour in charged macroion/counterion solutions.

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