Synthesis of Highly Insulated Molecular Wires by Polymerization of Organic‐Soluble Symmetrical Linked Inclusion Complex Monomers | Zendy

Terao Jun | Zendy; Tsuda Susumu | Zendy; Tsurui Keisuke | Zendy; Kambe Nobuaki | Zendy

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Synthesis of Highly Insulated Molecular Wires by Polymerization of Organic‐Soluble Symmetrical Linked Inclusion Complex Monomers

Author(s) -

Terao Jun,

Tsuda Susumu,

Tsurui Keisuke,

Kambe Nobuaki

Publication year - 2010

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.200900053

Subject(s) - monomer , polymerization , polymer chemistry , inclusion (mineral) , materials science , cyclodextrin , chemistry , polymer , organic chemistry , composite material , mineralogy

Summary: We developed a new method for synthesizing an organic‐soluble permethylated cyclodextrin‐based insulated molecular wire (IMW); this method involves the polymerization of a symmetrical linked inclusion complex as a monomer. This monomer was synthesized by dimerization of linked inclusion complexes at the terminal alkynyl groups by Glaser coupling. The polyrotaxane thus obtained is highly soluble in a variety of organic solvents and has a high covering ratio, regioregularity, and photoluminescence efficiency.

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