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Molecules‐Receptors: Different Approaches to Design Effective Catalysts
Author(s) -
Karakhanov Edward A.,
Karapetyan Lyusyen M.,
Kardasheva Yulia S.,
Maksimov Anton L.,
Runova Elena A.,
Terenina Maria V.,
Filippova Tatyana Yu.
Publication year - 2008
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200851013
Subject(s) - hydroformylation , catalysis , styrene , benzene , molecular imprinting , chemistry , molecule , combinatorial chemistry , oxidative coupling of methane , organic chemistry , selectivity , rhodium , copolymer , polymer
The results of studying a number of reactions catalyzed by system based on macrocyclic receptors are presented. Rh complexes with modified calix[6]‐ and calix[4]arene were active in the hydroformylation of unsaturated compounds. Ru catalytic system based on cucurbit[6]uril was studied in hydrogen transfer hydrogenation of water insoluble aldehydes. Molecular imprinting method application for design of catalytic systems based on cyclodextrins for naphthols dimerization and oxidative coupling styrene and benzene were discussed.