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Alternative Synthetic Routes to Epoxy Polymer – Clay Nanocomposites using Organic or Mixed‐Ion Clays Modified by Protonated Di/Triamines (Jeffamines)
Author(s) -
Triantafyllidis Kostas S.,
Xidas Panagiotis I.,
Pinnavaia Thomas J.
Publication year - 2008
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200850707
Subject(s) - nanocomposite , epoxy , materials science , curing (chemistry) , polymer , chemical engineering , polymer chemistry , ion exchange , ion , chemistry , organic chemistry , composite material , engineering
Abstract The use of homoionic organic clays and mixed‐ion organic/inorganic clays modified by di‐ or triamines (Jeffamines), which are being used as epoxy resin curing agents, in the synthesis of polymer nanocomposites has been studied in this work. Our aim is to enhance polymer crosslinking and interfacial adhesion in the nanocomposite structure by utilizing the functionality of the di/triamines on the surface of clay nanolayers and by reducing the organic modifier via formation of homostructured mixed‐ion organic/inorganic clays. The results show that the use of homoionic organic clays exchanged with relatively short chain di‐ or triamines and mixed‐ion organic/inorganic clays partially exchanged (ca. 35%) with long chain diamines resulted in intercalated structures with enhanced thermo‐mechanical properties (Young's Modulus, Storage Modulus). On the other hand, homoionic organic clays exchanged with long chain diamines and triamines resulted in exfoliated nanocomposites but with compromised mechanical properties due to the plasticizing effect of the long chain amine modifiers.