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Dye Sensitized Solar Cell Using Polymer Electrolytes Based on Poly(ethylene oxide) with an Ionic Liquid
Author(s) -
Singh Pramod K.,
Kim KiIl,
Park NamGyu,
Rhee HeeWoo
Publication year - 2007
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200750327
Subject(s) - dye sensitized solar cell , ionic liquid , crystallinity , materials science , electrolyte , ethylene oxide , thiocyanate , ionic conductivity , polymer , solar cell , doping , chemical engineering , fourier transform infrared spectroscopy , oxide , ionic bonding , conductivity , inorganic chemistry , polymer chemistry , ion , chemistry , organic chemistry , electrode , composite material , optoelectronics , copolymer , engineering , metallurgy , catalysis
Polymer electrolytes were prepared by doping PEO:KI/I 2 with an ionic liquid (IL) 1‐ethyl 3‐methylimidazolium thiocyanate (EMImSCN). FTIR confirmed composite nature while X‐ray diffraction (XRD) measurement affirmed the reduction in crystallinity, when IL was added. The ionic conductivity was improved by the addition of IL. The photoelectrochemical effect of the IL–doping in the terms of the current density J sc and efficiency of a dye sensitized solar cells (DSSC) has also been discussed.

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