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Synthesis of A New Terpyridine Ligand Combined with Ruthenium(II) Complex and its Usage in the Stepwise Fabrication of Complex Polymer Wires on Gold
Author(s) -
Ohba Yoshiki,
Kanaizuka Katsuhiko,
Murata Masaki,
Nishihara Hiroshi
Publication year - 2006
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200650305
Subject(s) - terpyridine , ruthenium , ligand (biochemistry) , redox , metal , materials science , polymer , combinatorial chemistry , fabrication , polymer chemistry , chemistry , nanotechnology , photochemistry , inorganic chemistry , catalysis , organic chemistry , metallurgy , composite material , medicine , biochemistry , receptor , alternative medicine , pathology
Abstract Summary: A ruthenium complex‐combined terpyridine ligand, tpyRu(dpp)‐(epe)‐ tpyPF 6 , was synthesized. Stepwise coordination reactions at the gold surface using this ligand gave Co‐Ru hetero‐metal complex wires, [ 1Co1Ru ], which underwent reversible redox reactions of both redox complex units.