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Urea‐Formaldehyde Microcapsules Containing an Epoxy Resin: Influence of Reaction Parameters on the Encapsulation Yield
Author(s) -
Cosco Simona,
Ambrogi Veronica,
Musto Pellegrino,
Carfagna Cosimo
Publication year - 2006
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200650224
Subject(s) - urea formaldehyde , epoxy , materials science , in situ polymerization , polymerization , formaldehyde , chemical engineering , emulsion polymerization , emulsion , interfacial polymerization , monomer , polymer chemistry , composite material , polymer , chemistry , organic chemistry , adhesive , layer (electronics) , engineering
In this work urea‐formaldehyde microcapsules containing an epoxy resin are prepared by in situ polymerization of monomers in an oil‐in‐water emulsion. Scanning electronic microscopy (SEM) was performed to investigate on microcapsule size and surface morphology. Calorimetric and spectroscopic analyses were carried out with the aim of evaluate the encapsulation yield and the shell features. Factors determining the microencapsulability of the core material were described. In particular, our interest was devoted to a better understanding of the influence of the reaction parameters on the microcapsule properties. It was found that the encapsulation yield as well as the extent of urea‐formaldehyde polymerization depends on the reaction temperature and the stirring speed.