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Advances and Limits in Copolymerization of Olefins with Conjugated Dienes
Author(s) -
Boisson Christophe,
Monteil Vincent,
Thuilliez Julien,
Spitz Roger,
Monnet Christiane,
Llauro MarieFrance,
Barbotin Fanny,
Robert Pierre
Publication year - 2005
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200550802
Subject(s) - copolymer , conjugated system , catalysis , polymerization , metallocene , lanthanide , post metallocene catalyst , polymer chemistry , olefin fiber , polymer , materials science , olefin polymerization , polymer science , organic chemistry , chemistry , ion
The field of the copolymerization of olefins with conjugated dienes has been investigated. While the insertion of butadiene is often limited with most catalyst systems designed for olefin polymerization, lanthanide metallocene catalysts insert butadiene with good efficiency. In the present paper, the preparation of a vast range of products including new polymers is reviewed.