Thermodynamic and Kinetic Polymerizability of Cyclic Esters | Zendy

Duda Andrzej | Zendy; Kowalski Adam | Zendy; Libiszowski Jan | Zendy; Penczek Stanislaw | Zendy

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Thermodynamic and Kinetic Polymerizability of Cyclic Esters

Author(s) -

Duda Andrzej,

Kowalski Adam,

Libiszowski Jan,

Penczek Stanislaw

Publication year - 2005

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.200550607

Subject(s) - polymerization , monomer , ring opening polymerization , polymer chemistry , kinetics , chirality (physics) , chemistry , kinetic energy , lactide , materials science , organic chemistry , polymer , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark

Recent advances in the controlled ring‐opening polymerization (ROP) of cyclic aliphatic esters are reviewed with a particular attention to thermodynamics and kinetics of the polymerization of industrially important monomers, namely: lactide (LA), 1,4‐dioxan‐2‐one (DX), and ϵ‐caprolactone (CL). For comparison, polymerization of β‐lactones is discussed. Progress in stereocontrolled polymerization of monomers bearing centers of chirality [LA and β‐butyrolactone (BL)] is also briefly reviewed.

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