Premium
NMR Spectroscopy and Atomic Force Microscopy Characterization of Hybrid Organic – Inorganic Coatings
Author(s) -
Brus Jiří,
Špírková Milena
Publication year - 2005
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200550212
Subject(s) - organosilicon , spectroscopy , atomic force microscopy , materials science , chemical engineering , nuclear magnetic resonance spectroscopy , characterization (materials science) , chemistry , nanotechnology , polymer chemistry , organic chemistry , physics , quantum mechanics , engineering
Hybrid organic–inorganic (O‐I) epoxide‐based products made from functionalized organosilicon precursors, oligomeric di‐ and triamines and in some cases colloidal silica particles were characterized by NMR spectroscopy and atomic force microscopy (AFM). The kinetics and reaction mechanism of condensation reactions, structure and segmental dynamics of final films, as well as homogeneity and partial ordering were studied by solid‐state NMR spectroscopy (2D CRAMPS, 2D 1 H‐ 13 C WISE, relaxation experiments); the surface morphology and other surface characteristics were determined by AFM.