Polymerization with Fischer‐Tropsch olefins – a new challenge in polymer science | Zendy

Tincul Ioan | Zendy; Lufuno Siphuma | Zendy; Rawatlal Randhir | Zendy

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Polymerization with Fischer‐Tropsch olefins – a new challenge in polymer science

Author(s) -

Tincul Ioan,

Lufuno Siphuma,

Rawatlal Randhir

Publication year - 2004

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.200450932

Subject(s) - fischer–tropsch process , polymerization , ethylene , catalysis , titanium , titanium tetrachloride , polymer , olefin fiber , natta , materials science , ziegler–natta catalyst , polymer chemistry , organic chemistry , chemistry , chemical engineering , selectivity , engineering

Co‐ and ter‐polymerization of ethylene with Fischer‐Tropsch derived olefins having odd carbon number and branched olefins are investigated. A method of preparation of a robust, high productivity Ziegler‐Natta catalyst suitable for ethylene co‐polymerization with Fischer Tropsch olefin is reviewed. In supporting titanium tetrachloride, an attempt was made to control the titanium oxidation state. The resulting experimental data were fitted to a sub‐sites model that associates titanium oxidation state with catalyst activity.

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