Premium
Luminescence properties of organometallic/coordination oligomers and polymers containing diphosphine and diisocyanide assembling ligands: comparison between mononuclear model complexes and polymers
Author(s) -
Harvey Pierre D.
Publication year - 2004
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200450506
Subject(s) - propane , polymer , butane , luminescence , platinum , acetylene , chemistry , polymer chemistry , pentane , hexane , bridging ligand , ligand (biochemistry) , photochemistry , materials science , metal , organic chemistry , catalysis , biochemistry , receptor , optoelectronics
This paper describes the luminescence properties of selected examples of homo‐ and mixed‐bridging ligand‐containing organometallic/coordination oligomers and polymers of copper(I), silver(I), palladium(I) and −(0.5), and platinum(0.5). The bridging ligands are the 1,8‐diisocyano‐p‐menthane (dmb) and bis(diphenylphosphino)methane (dppm), ‐ethane (dppe), ‐propane (dppp), ‐butane (dppb), ‐pentane (dpppen), and −hexane (dpph), as well as bis(diphenyl‐phosphino)acetylene (dpa) and bis(dimethylphosphino)methane (dmpm). The comparison between the mononuclear model complexes and the polymers of the emission maxima (λ max ) and emission lifetimes (τ e ) will be made, and interpreted by the presence of intrachain interactions and exciton phenomena.