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Nanostructured polymer gels
Author(s) -
Hu Zhibing
Publication year - 2004
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200450305
Subject(s) - covalent bond , polymer , gelatin , materials science , dispersity , polymer science , nanoparticle , chemical engineering , polymer chemistry , iridescence , nanotechnology , chemistry , composite material , organic chemistry , optics , physics , engineering
A brief review of our recent work on polymer gel opals is given in memory of late Professor Tanaka. The central idea is to first synthesize monodisperse polymer gel nanoparticles, then self‐assemble them into a 3D network, and eventually covalently bond them. The covalent bonding contributes to the structural stability, while self‐assembly provides them with crystal structures that diffract light, resulting in colors. N‐isopropylacrylamide (NIPA) gel has been used as a model system for this study. The nanostructured NIPA gel, which contain up to 97 wt% water, displays a striking iridescence like precious opal but are soft and flexible like gelatin.