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Phosphine‐based coordination cages and nanoporous coordination polymers
Author(s) -
James Stuart L.,
Xu Xingling,
Law Robert V.
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200390159
Subject(s) - polymer , denticity , nanoporous , phosphine , coordination polymer , materials science , porosity , organic polymer , metal , coordination complex , polymer chemistry , nanotechnology , polymer science , chemistry , organic chemistry , composite material , metallurgy , catalysis
Recent findings in the use of multidentate phosphines to synthesise porous coordination polymers (metal‐organic frameworks) and their possible precursor cages are reviewed. Additional recent investigations into using large adamantoid Age cages as polymer vertices in giant diamandoid structures are also presented. The results are discussed in terms of possible strategies for the controled synthesis of porous coordination polymers.