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Coordination/organometallic polymers based on diphosphine and diisocyanide ligands
Author(s) -
Harvey Pierre D.
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200390158
Subject(s) - diphosphines , chemistry , acetylene , alkane , group 2 organometallic chemistry , organometallic chemistry , transition metal , polymer , metal , palladium , methane , stereochemistry , polymer chemistry , crystallography , catalysis , molecule , organic chemistry , crystal structure
Abstract This paper reviews various coordination/ organometallic polymers in which the metal atoms are incorporated in the backbone using diphosphine and diisocyanide ligands. Such ligands includes diphosphines of the type bis(diphenylphosphino)alkane where alkane is (CH 2 ) m with m = 1, 3‐6, bis(diphenylphosphino)acetylene (dpa), and bis(dimethylphosphino)methane (dmpm), and diisocyanides such as 1,8‐diiso‐cyano‐ p ‐menthane (dmb) and p ‐diisocyanotetra‐methylbenzene (ditmb). The metal fragments are monocations such as Cu + , Ag + , and Au + , dinuclear species such as Pd 2 (dmb) 2 2+ , Pd 2 (dppm) 2 2+ , M 2 (dmpm) 3 2+ (M = Cu, Ag), and clusters such as M 4 (dmb) 4 2+ (M = Pd, Pt).