Electron transport in conjugated metallopolymers | Zendy

Cameron Colin G. | Zendy; MacLean Brian J. | Zendy; Pickup Peter G. | Zendy

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Electron transport in conjugated metallopolymers

Author(s) -

Cameron Colin G.,

MacLean Brian J.,

Pickup Peter G.

Publication year - 2003

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.200390157

Subject(s) - superexchange , conjugated system , electron transport chain , polymer , electron , metal , bipyridine , materials science , photochemistry , chemical physics , chemistry , crystallography , organic chemistry , physics , ion , crystal structure , biochemistry , quantum mechanics

Superexchange interactions between metal centers coordinated to various conjugated polymer backbones have been shown to enhance the rate of electron transport through the polymer. Results for Ru and Os bipyridine moieties complexed to polybenzimidzoles and poly(bithiophene‐co‐bithiazole)s are reviewed. The evidence for superexchange mediated electron transport, and the factors that influence the rate of electron hopping between metal centers, are discussed.

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