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Polyfunctional activity of metal complexes containing 2,6‐Di‐ tert ‐butylphenol in catalytic oxidation
Author(s) -
Milaeva Elena R.,
Shpakovsky Dmitry B.,
Petrosyan Valery S.
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200351416
Subject(s) - catalysis , chemistry , reactivity (psychology) , ligand (biochemistry) , redox , metal , aryl , catalytic oxidation , transition metal , polymer chemistry , oxygen , homogeneous , organic chemistry , group 2 organometallic chemistry , homogeneous catalysis , photochemistry , molecule , medicine , biochemistry , alkyl , alternative medicine , receptor , physics , pathology , thermodynamics
The results of the investigations of metal complexes containing 2,6‐di‐ tert ‐butilphenol in the ligand environment in catalytic homogeneous oxidation of organic compounds are reviewed. The liquid‐phase oxidation of hydrocarbons, olefins, aminophenol and unsaturated fatty acids by molecular oxygen in the presence of phthalocyanines, porphyrins, σ‐aryl and π‐allyl transition metal complexes is described. The change of the reactivity of organometallic and coordination compounds by oxidation of the redox active phenolic group opens up the possibility to use them as polyfunctional catalytic systems showing positive and/or negative catalytic effects.