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Supramolecular catalytic systems based on calixarenes and cyclodextrins
Author(s) -
Karakhanov Edward E.,
Maksimov Anton L.,
Runova Elena A.,
Kardasheva Yulia S.,
Terenina Maria F.,
Buchneva Tatyana S.,
Guchkova Anna Ya.
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200351414
Subject(s) - supramolecular chemistry , calixarene , supramolecular catalysis , hydroformylation , catalysis , combinatorial chemistry , cyclodextrin , molecule , molecular recognition , metal , chemistry , selectivity , materials science , organic chemistry , rhodium
A number of supramolecular metal complex catalitic system based on cyclodextrins and calixarenes have been developed. Particular attention has been given to design of new metal complexes with molecular recognition abilities. Data on application catalytic systems based on receptor molecules capable to formation of inclusion “host‐guest” complexes in hydroformylation and Wacker‐oxidation are given. Influence of different factors on activity, stability, selectivity of metal complex supramolecular catalytic systems is discussed.