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Synthesis of azo‐conjugated catecholate complexes and their photo‐ and proton‐responses
Author(s) -
Nagashima Sayoko,
Nihei Masayuki,
Yamada Teppei,
Murata Masaki,
Kurihara Masato,
Nishihara Hiroshi
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200351409
Subject(s) - conjugated system , photoisomerization , proton , nickel , ligand (biochemistry) , chemistry , photochemistry , materials science , isomerization , polymer , organic chemistry , catalysis , receptor , physics , quantum mechanics , biochemistry
A new azo‐conjugated catecholate ligand, azocat , and its nickel complexes were synthesized, and their physical and chemical properties were investigated. The complex with one azocat shows no obvious photo‐response, whereas the compound with two azocat 's causes a little photoisomerization. Both of these novel azo‐conjugated catecholate complexes show remarkable proton responses.