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Blends of isotactic polypropylenes and a plastomer: crystallization and viscoelastic behavior
Author(s) -
Cerrada Maria L.,
Prieto Oscar,
Pereña José M.,
Benavente Rosario,
Pérez Ernesto
Publication year - 2003
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.200350809
Subject(s) - materials science , tacticity , copolymer , viscoelasticity , crystallization , dynamic mechanical analysis , composite material , toughness , polymer blend , miscibility , polymer chemistry , polymer , thermodynamics , polymerization , physics
Blends covering the entire range of compositions of a metallocenic ethylene‐1‐octene, CEO, copolymer and two conventional isotactic polypropylenes, iPP, of different molecular weights have been prepared, analyzing the effect of composition and molecular weight on the crystallization (studied by DSC and X‐ray diffraction) and viscoelastic behavior (DMTA). It was found that those blends rich in the iPP component show a behavior practically coincident with the weighted addition of the two components. On the contrary, significant deviations were found for the blends where the CEO copolymer is the major component. These deviations are considerably more important in the case of the blends with the iPP of higher molecular weight. Moreover, both components are not miscible, exhibiting the glass transitions of the two neat components. The area under the loss tangent curves provides a preliminary information about how the toughness is enhanced using this type of impact modifier, though it provokes a significant reduction of stiffness.