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Multifunctional polyurethane network structures
Author(s) -
Fedderly Jeffry J.,
Lee Gilbert F.,
Lee John D.,
Hartmann Bruce,
Dušek Karel,
Šomvársky Ján,
Smrčková Miroslava
Publication year - 1999
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19991480103
Subject(s) - glass transition , materials science , branching (polymer chemistry) , polyurethane , dynamic mechanical analysis , elastomer , stoichiometry , polymer chemistry , composite material , chemical engineering , chemistry , polymer , engineering
A series of thirteen polyurethanes were synthesized using blends of monofunctional, difunctional, and trifunctional poly(propylene oxides) reacted with 4,4'‐diphenylmethane diisocyanate in a stoichiometric ratio. Experimental measurements were made of glass transition temperature, sol fraction, and dynamic mechanical properties. Computer simulations based on the theory of branching processes were made on the same systems. The glass transition temperature was correlated with the number average functionality of the components. Dynamic mechanical data was fitted to the Havriliak‐Negami model. A correlation was demonstrated between the measured rubbery modulus and the concentration of elastically active network chains.