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Cluster carbonyls of Os, Fe and Fe‐Rh on oxide supports: Synthesis and properties
Author(s) -
Kuznetsov Boris N.,
Kovalchuk Vladimir I.,
Chesnokov Nikolai V.,
Mikova Nadezhda M.,
Naimushina Lilia V.
Publication year - 1998
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19981360109
Subject(s) - x ray photoelectron spectroscopy , thermal desorption spectroscopy , catalysis , cluster (spacecraft) , oxide , desorption , mössbauer spectroscopy , materials science , spectroscopy , thermal desorption , high resolution , inorganic chemistry , chemistry , nuclear chemistry , chemical engineering , crystallography , adsorption , organic chemistry , metallurgy , physics , quantum mechanics , computer science , engineering , programming language , remote sensing , geology
Surface nano‐size structures have been obtained by supporting on oxide supports (SiO 2 , MgO, Al 2 O 3 ) some cluster carbonyls of Os, Fe, Fe‐Rh and by their following thermal conversions. Surface species were characterized by IR‐spectroscopy, high‐resolution TEM, XPS, Mössbauer spectroscopy and temperature‐programmed desorption technique. Their catalytic properties was studied in CO hydrogenation reaction.