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Electron transfer in some nucleophilic reactions
Author(s) -
Lund Henning,
Daasbjerg Kim,
Lund Torben,
Pedersen Steen U.
Publication year - 1998
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19981340109
Subject(s) - nucleophile , electron transfer , electron , photochemistry , chemistry , materials science , physics , organic chemistry , nuclear physics , catalysis
Using kinetic, steric and thermodynamic results it is argued that the rate‐determining step in some aliphatic, nucleophilic substitutions is the transfer of an electron.