Premium
Dodecyl dodecanamide as a model for the study of polyamide n‐chlorination. Unusual behaviors of the reaction system
Author(s) -
Girardon V.,
Tessier M.,
Maréchal E.
Publication year - 1997
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19971220149
Subject(s) - iodometry , polyamide , reagent , chemistry , titration , chloride , methylene , methylene blue , sodium hypochlorite , hypochlorite , nuclear chemistry , polymer chemistry , organic chemistry , catalysis , photocatalysis
The N‐chlorination of dodecyl dodecanamide (DDA) by ter ‐butyl hypochlorite (tBuOCl) was carried out at 25°C in methylene chloride. The conversion is determined by 1 H‐NMR and iodometric titrations of N‐chlorinated DDA (N‐Cl DDA). Curves of conversion‐time plots present singular profiles whose shapes are strongly depending on the reagent and product concentrations.