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Organometallic reactions as tools to build new metal‐containing conjugated polymers
Author(s) -
Lavastre O.,
Even M.,
Troccon C.,
Dixneuf P. H.,
Pacreau A.,
Vairon JP.
Publication year - 1997
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19971220112
Subject(s) - monomer , conjugated system , organometallic chemistry , metal , polymer , group 2 organometallic chemistry , condensation polymer , coupling reaction , polymer chemistry , bond cleavage , chemistry , catalysis , carbon fibers , silicon , materials science , organic chemistry , molecule , composite number , composite material
By using organometallic reactions like Pd‐catalyzed C‐C coupling, metal‐carbon bond formation and silicon‐carbon bond cleavage, novel carbon‐rich organometallic monomers HC≡C‐C 6 H 4 ‐C≡C‐[M]‐C≡C‐C 6 H 4 ‐C≡CH ( [M] = ‐Ru(dppe) 2 ‐ and (η 5 ‐C 5 H 4 ) 2 Fe) and organic monomers H‐(C≡C‐C 6 H 4 ) X ‐C≡CH (x = 1 to 3) have been obtained. They have been used for the design of novel homo and hetero metal‐containing polymers via organometallic polycondensation reactions based on quantitative metal‐carbon bond formation.