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Synthesis of metal‐complexes and their reactivities: ‐The difference of reactivities among the manganese complexes‐
Author(s) -
Kurusu Yasuhiko
Publication year - 1996
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19961050124
Subject(s) - manganese , chemistry , autoxidation , chelation , potassium permanganate , magnesium , acetic acid , inorganic chemistry , benzene , induction period , metal , molecule , isopropyl , permanganate , manganese(iii) acetate , polymer chemistry , nuclear chemistry , medicinal chemistry , organic chemistry , catalysis
Manganese chelates were prepared and the autoxidation of isopropyl benzene (IP) was carried out. (Mn‐Chelate‐1) showed a long induction period, but the other complexes (Mn‐Chelate‐2 and −3) which contain two or more magnesium ions in each molecule had shorter induction periods. The difference comes from the conformation around the manganese ion. Mn(III) acetate prepared from the oxidation of manganese (II) acetate with potassium permanganate in acetic acid was discussed.