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Macromolecularization of fullerenes and the charge transfer complex formation of fullerenes with polymers having electron‐donating or electron‐accepting moieties
Author(s) -
Li FuMian
Publication year - 1996
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19961010126
Subject(s) - moiety , polymer chemistry , fullerene , chromophore , materials science , polymer , copolymer , methacrylate , styrene , photochemistry , fullerene chemistry , chemistry , organic chemistry , composite material
C 60 was bonded to allylamine homopolymer (PALA) and its copolymers with styrene, 2‐hydroxypropyl methacrylate etc. as a pendant functional group. The polyallylamine bonded C 60 displays fluorescence at room temperature although C 60 does not in itself. This may be due to the lessening of highly symmetrical shape of C 60 . Some C 60 ‐amine adducts are prepared as the model of polyallylamine‐C 60 for the clarification. C 60 doped poly(tetrahydrofurfuryl methacrylate) film has been prepared and its optical non‐linearity has been investigated. The charge transfer complexes formation of C 60 with polymers having electron‐donating chromophore moieties such as poly(dimethylaminostyrene), poly(acryloylphenothiazine), poly(acryloylphenoxazine) and poly(styrene‐co‐dimethylaminophenylmaleimide) as well as with polymer having electron‐accepting chromophore moiety poly(cyanophenylacrylamide) have been manifested.