Spontaneous copolymerizations in the reactions of electronrich dienes with electrophilic olefins | Zendy

Hall H. K. | Zendy; Padias Anne Buyle | Zendy

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Spontaneous copolymerizations in the reactions of electronrich dienes with electrophilic olefins

Author(s) -

Hall H. K.,

Padias Anne Buyle

Publication year - 1995

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.19950980110

Subject(s) - diradical , electrophile , reactivity (psychology) , copolymer , chemistry , reaction mechanism , polymer chemistry , photochemistry , organic chemistry , catalysis , polymer , physics , excited state , medicine , alternative medicine , pathology , nuclear physics , singlet state

The spontaneous thermal reactions of electron‐rich dienes with electrophilic olefins lead to both [4+2] cycloadducts and copolymers. The mechanism proposed for the initiation of the copolymerization involves the formation of a 2‐hexene‐1, 6‐diradical. Structure‐reactivity relationships are discussed.

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