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Ring‐opening metathesis copolymerization employing ruthenium‐based metathesis catalysts
Author(s) -
Hillmyer Marc A.,
Benedicto Alto D.,
Nguyen SonBinh T.,
Wu Zhe,
Grubbs Robert H.
Publication year - 1995
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19950890138
Subject(s) - ruthenium , carbene , metathesis , copolymer , catalysis , ring opening metathesis polymerisation , acyclic diene metathesis , ligand (biochemistry) , polymer chemistry , ring closing metathesis , materials science , combinatorial chemistry , chemistry , organic chemistry , polymerization , polymer , biochemistry , receptor
The copolymerization of both high‐ and low‐strain cyclic olefins employing three ruthenium‐based metathesis catalysts is desribed. The effect of the ligand environment as well as the nature of the carbene on the copolymerizations is discussed.