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The catalysis of the stereospecific butadiene polymerization by Allyl Nickel and Allyl Lanthanide complexes — A mechanistic comparison
Author(s) -
Taube Rudolf,
Windisch Heike,
Maiwald Steffen
Publication year - 1995
Publication title -
macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 1022-1360
DOI - 10.1002/masy.19950890137
Subject(s) - stereospecificity , polymerization , catalysis , lanthanide , 1,3 butadiene , nickel , chemistry , reactivity (psychology) , polymer chemistry , organic chemistry , polymer , medicine , ion , alternative medicine , pathology
A short overview on the general mechanistic principles of the allyl metal complex catalyzed stereo‐specific butadiene polymerization is given. The present state of knowledge on the mechanism of stereoregulation and in the understanding of the catalytic structure reactivity relationships is discussed comparatively for allyl nickel and allyl lanthanide catalysts.