New cationic group 4 metal alkyl complexes | Zendy

Tjaden Erik B. | Zendy; Jordan Richard F. | Zendy

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New cationic group 4 metal alkyl complexes

Author(s) -

Tjaden Erik B.,

Jordan Richard F.

Publication year - 1995

Publication title -

macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 1022-1360

DOI - 10.1002/masy.19950890123

Subject(s) - cationic polymerization , alkyl , protonolysis , polymer chemistry , chemistry , metal , electrophile , catalysis , ethylene , group (periodic table) , schiff base , main group element , polymerization , base (topology) , organic chemistry , transition metal , polymer , mathematical analysis , mathematics

Cationic group 4 metal alkyl complexes containing tetradentate Schiff base ligands, (acen) Zr(R) + and (F6‐acen) Zr(R) + , are prepared by protonolysis of suitable neutral dialkyl precursors. These complexes display electrophilic behavior and are moderately active ethylene polymerization catalysts in the presence of 1 molar equivalent of AlR 3 .

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