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Synthesis and characterization of polymers from itaconic acid derivatives
Author(s) -
Otsu Takayuki,
Watanabe Hiroyuki,
Yang JianZhong,
Yoshioka Masahiro,
Matsumoto Akikazu
Publication year - 1992
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19920630109
Subject(s) - itaconic acid , polymerization , monomer , polymer , chemistry , reactivity (psychology) , polymer chemistry , alkyl , organic chemistry , medicine , alternative medicine , pathology
Some itaconic acid derivatives were prepared and polymerized, in which itaconic acid (IA), β ‐monoalkyl itaconates (mRI), dialkyl itaconates (DRI), N ‐substituted itaconamates (IAE), itaconamides (IAm), itaconic anhydride (IAn), N ‐alkylitaconimides (RII), and N ‐(alkyl‐substituted phenyl)itaconimides (RPhII) are included. The polymerization reactivity was examined, and discussed in relation to the structure of the monomers. The structure and some properties of the resulting polymers were investigated. Some citraconic acid (CA) and mesaconic acid (MA) derivatives were also polymerized, and their reactivities were compared with the corresponding IA derivatives.