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The role of ceric ion in vinyl polymerization and graft copolymerization
Author(s) -
Qiu KunYuan
Publication year - 1992
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19920630108
Subject(s) - ceric ammonium nitrate , copolymer , chemistry , polymer chemistry , polymerization , materials science , organic chemistry , polymer
Six kinds of new ceric ion redox initiation systems for vinyl radical polymerization and two kinds of macromolecule graft copolymerization by ceric ion have been briefly reviewed in this paper. The initiators include ceric ion/acetanilide, ceric ion/alkyl phenylcarbamate, ceric ion/4‐methoxysuccinyltoluidine, ceric ion/aliphatic aldehyde, ceric ion/aromatic aldehyde, ceric ion/diketone systems. Macromolecules such as poly(ether‐urethane) and macromolecules having active pendant groups were selected for graft copolymerization with acrylamide initiated by ceric ion.