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Zwitterionic chain polymerizations of cyanoacrylates
Author(s) -
Pepper D. C.
Publication year - 1992
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19920600124
Subject(s) - cyanoacrylates , alkyl , polymer science , mechanism (biology) , kinetics , chemistry , polymer chemistry , materials science , organic chemistry , philosophy , epistemology , physics , cyanoacrylate , adhesive , layer (electronics) , quantum mechanics
The lecture reviews recent studies on vinyl and vinylidene compounds, chiefly alkyl cyanoacrylates. It emphasizes the kinetics, especially the distinctive SINT (slow‐initiation‐no‐termination) pattern, and the composite mechanism of initiation by tertiary amines. The need for corroboration of interpretations, clarification of ambiguities and extensions is emphasized.