Functionalization of silica (II) ‐ oxidation of cyclohexanes in the presence of functionalized silica complexed by iron and copper | Zendy

Kurusu Yasuhiko | Zendy

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Functionalization of silica (II) ‐ oxidation of cyclohexanes in the presence of functionalized silica complexed by iron and copper

Author(s) -

Kurusu Yasuhiko

Publication year - 1992

Publication title -

makromolekulare chemie. macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 0258-0322

DOI - 10.1002/masy.19920590125

Subject(s) - copper , cyclohexanes , surface modification , methylcyclohexane , yield (engineering) , chemistry , silica gel , catalysis , polymer chemistry , oxygen , inorganic chemistry , nuclear chemistry , materials science , organic chemistry , metallurgy

Silica gel was modified with (N,N‐dimethyl‐3‐ aminopropyl)trimethoxysilane and the functionalized silica catalysts thus prepared complexed with iron and copper to produce FS‐1{Fe},FS‐1{Cu}. 11.2% of methylcyclohexane was oxidized in the presence of oxygen with FS‐1(Fe) at 60°C. 2‐Hydroxymethylcyclohexane was obtained in 59% yield. The structural differences between FS‐1 (Fe)and FS‐1 {Cu} are discussed.

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