Molecular architecture control in acrylic polymers by group transfer polymerization | Zendy

Webster Owen W. | Zendy

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Molecular architecture control in acrylic polymers by group transfer polymerization

Author(s) -

Webster Owen W.

Publication year - 1992

Publication title -

makromolekulare chemie. macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 0258-0322

DOI - 10.1002/masy.19920530128

Subject(s) - silylation , polymerization , nucleophile , polymer , polymer chemistry , copolymer , methyl methacrylate , end group , chain transfer , materials science , catalysis , chemistry , radical polymerization , organic chemistry

The living polymerization of methacrylates by a repeated silyl Michael addition reaction (GTP) a operates at room temperature and permits a high degree of molecular architecture control. Chelic, telechelic, block, comb, star, loop, and ladder polymers have been synthesized. For nucleophilic catalysts other than bifluoride, a dissociative mechanism is now proposed.

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