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Synthesis and investigation of new organometallic polymers on the basis of polyacrylonitrile
Author(s) -
Valetsky P. M.,
Bronstein L. M.,
Loginova T. P.
Publication year - 1991
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19910440123
Subject(s) - polyacrylonitrile , nitrile , group 2 organometallic chemistry , polymer chemistry , chromium , metal , polymer , chemistry , materials science , inorganic chemistry , organic chemistry , molecule
The regularities of complex formation of PAN nitrile groups with hexacarbonyls of VIB group metals were studied. PAN metal carbonyl complexes with various degrees of complexation were synthesized. Thermal transformations of PAN metal carbonyls were investigated. It was shown that the thermal changes of PAN chromium carbonyls are anomalous, but this does not prevent from the formation of polyconjugated areas and the enchancement of conductivity.