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Some monomers, oligomers and polymers with conjugated triple bonds
Author(s) -
Giesa Reiner,
Klapper Markus,
Schulz Rolf C.
Publication year - 1991
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19910440102
Subject(s) - diacetylene , polydiacetylenes , monomer , polymer , triple bond , polymer chemistry , conjugated system , acetylene , materials science , copolymer , phenylene , photochemistry , chemistry , polymer science , organic chemistry , double bond , composite material
In the first part new monoaminodiacetylenes with different numbers of CH 2 ‐groups, the formation of Perowskit‐type Mn complexes and their polymerizability are described. Symmetrical diaminodiacetylenes and some derivatives therefrom have also been prepared. The second part deals with different types of polymers with diacetylene units in the backbone. Under irradiation color formation and crosslinking take place. Well‐defined low molecular weight model compounds of polydiacetylenes is the subject of the third part. Finally rod‐like but soluble polymers with alternating p‐phenylene and acetylene units are described.