Premium
Synthetic importance and industrial applications of ring‐opening polymerization
Author(s) -
McGrath James E.
Publication year - 1991
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19910420106
Subject(s) - cationic polymerization , silicone , materials science , siloxane , polymerization , monomer , polycaprolactone , polymer chemistry , polymer , ring opening polymerization , oxetane , polyamide , polymer science , epoxy , polyester , composite material
A survey is provided which demonstrates the synthetic importance and variety of industrial applications that have developed for ring‐opening polymerization. The number of polymers produced this way is quite significant and includes the epoxides such as ethylene and propylene oxide and other cyclic ethers such as trioxane, tetrahydrofuran and the epoxy resins. Other important systems include the polylactams such as polycaprolactam (Nylon 6), the siloxane or silicone materials, polycaprolactone, and cycloolefins such as polynorbornene. Polyoxazolines are newer monomers which can be polymerized via cationic mechanisms to yield either hydrophilic or hydrophobic tertiary polyamides. Thus, the importance of the field is quite well established and continues to grow. Major applications in coatings, fibers, elastomers, adhesives, thermoplastics and thermosets, such as in composite matrix resins, have been developed.