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Molecular aspects of polymer network deformation ‐ small angle neutron scattering and NMR studies
Author(s) -
Gronski W.,
Forster F.,
PyckhoutHintzen W.,
Springer T.
Publication year - 1990
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19900400113
Subject(s) - radius of gyration , neutron scattering , isotropy , anisotropy , materials science , small angle neutron scattering , rubber elasticity , monte carlo method , polymer , chain (unit) , deformation (meteorology) , gyration , scattering , molecular physics , crystallography , physics , chemistry , optics , composite material , geometry , astronomy , statistics , mathematics
Poly(1,4‐butadiene) networks obtained by a 4‐functional random cross‐linking reaction over a broad range of polymer concentration were studied by small angle neutron scattering(SANS), 2 H NMR and Monte Carlo(MC) simulation in the isotropic and uniaxially deformed state. The defect structure of the networks has been characterized by MC simulation of the cross‐linking reaction. The anisotropy of the radius of gyration in deformed networks determined from SANS has been analyzed by the theory of Ullman. It was found that the number of active cross‐links per chain is in agreement with MC and that the chain deformation follows phantom behaviour. The local orientation as measured by 2 H NMR is related to the global anisotropy of the network by a MC calculation of oriented chains. The 2 H NMR line shape of the deformed network is analyzed in terms of two relaxation processes arising from interior parts of the chains and from segments at chain ends. The mobility of both decrease with strain. It was found that the orientation connected to the first process shows the classical strain dependence of rubber elasticity, whereas the second exhibits a weaker dependence on strain.