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Networks from cyanic acid esters and glycidyl ethers
Author(s) -
Bauer M.,
Bauer J.
Publication year - 1989
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19890300103
Subject(s) - kinetics , chemistry , chemical kinetics , cascade , organic chemistry , process (computing) , computational chemistry , chemical engineering , computer science , chromatography , engineering , physics , quantum mechanics , operating system
Abstract Polycyanurates were prepared by polycyclotrimerization of aromatic dicyanates in bulk. The reaction kinetics and the resulting build‐up of a trifunctional network was modelled. Modified polycyanurates were synthesized by a co‐reaction of dicyanates with diglycidyl ethers. The statistics of the resulting network building process was modelled by cascade theory combined with a model of the kinetics of structural elements. The good agreement between theory and experiment is shown.